Which intermolecular force is strongest in alkenes and alkynes?

Study for the NCEA Level 2 Organic Chemistry Exam. Review key concepts with flashcards and multiple choice questions, each with detailed explanations. Get prepared for your exam success!

The strongest intermolecular force present in alkenes and alkynes is the instantaneous - induced dipole interaction, often referred to as London dispersion forces. These forces arise from the temporary fluctuations in electron density within molecules, leading to the formation of instantaneous dipoles.

In alkenes and alkynes, which are primarily composed of carbon and hydrogen, the molecular structure is nonpolar due to the symmetrical distribution of electrons. While they may not exhibit significant dipole-dipole interactions or hydrogen bonding (as these require polar functional groups or the presence of N-H, O-H, or F-H bonds), they do engage in London dispersion forces.

As the molecular mass increases, the strength of these instantaneous - induced dipole forces also increases, making larger alkenes and alkynes exhibit stronger dispersion interactions compared to smaller ones. This is particularly significant in organic compounds, where other types of bonding are not as prevalent.

Hydrogen bonding, dipole-dipole interactions, and ionic bonding are not applicable here since alkenes and alkynes lack the necessary functional groups and charge separation to engage in those interactions. Thus, instantaneous - induced dipole interactions are indeed the predominant forces at play in the intermolecular interactions of these hydrocar

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